課程資訊
課程名稱
高等物理化學一
Advanced Physical Chemistry (Ⅰ) (Chem. Thermodynamics)(Ⅰ) 
開課學期
109-1 
授課對象
工學院  分子科學與技術國際研究生博士學位學程  
授課教師
鄭原忠 
課號
Chem7031 
課程識別碼
223EM1310 
班次
 
學分
3.0 
全/半年
半年 
必/選修
選修 
上課時間
星期二6,7(13:20~15:10)星期四2(9:10~10:00) 
上課地點
化121化121 
備註
本課程以英語授課。外系所學生選修需經授課教師同意。 本班英文授課。
限碩士班以上 且 限本系所學生(含輔系、雙修生)
總人數上限:30人 
Ceiba 課程網頁
http://ceiba.ntu.edu.tw/1091APCI2020 
課程簡介影片
 
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課程概述

This course covers the principles and methods of equilibrium statistical mechanics for applications to chemical physics problems. The lectures will be divided into three parts: (1) A short review of thermodynamics principles. (2) The concepts of ensemble theory and the applications to gas, liquid, and solid systems. The Landau theory of phase transition will be discussed. (3) The final part will introduce the phase transition dynamics and the theory of Brownian motion.

Planned topics: laws of thermodynamics, thermal equilibrium and temperature, ensemble theory, entropy, non-interacting systems (gas and solid), chemical equilibrium, Ising models, imperfect gases, ionic solutions, Landau theory, dynamics of phase transition, Langevin equation and Brownian motion. 

課程目標
This course aims to introduce basic concepts of equilibrium statistical mechanics and selective topics of the dynamic theories for physical chemistry in the graduate level. 
課程要求
待補 
預期每週課後學習時數
 
Office Hours
 
指定閱讀
 
參考書目
Textbooks:

Introduction to Modern Statistical Mechanics, David Chandler, Oxford University Press.

Introduction to the theory of soft matter, Jonathan V. Selinger, Springer.

References:

Statistical Mechanics, Donald Allan McQuarrie, University Science Books; 2nd edition.

Statistical Physics of Particles, Tehran Kardar, Cambridge University Press. 
評量方式
(僅供參考)
   
課程進度
週次
日期
單元主題
Week 1
9/15  Notions of statistical thermodynamics (no class on 9/17) 
Week 2
9/22,9/24  Laws of thermodynamics 
Week 3
9/29,10/01  Fundamental equations of thermodynamics (no class on 10/1) 
Week 4
10/06,10/08  Equilibrium and stability, Statistical methods and ensemble 
Week 5
10/13,10/15  The canonical ensemble 
Week 6
10/20,10/22  Entropy and free energy functions 
Week 7
10/27,10/29  Statistics of particles 
Week 8
11/03,11/05  Photon gas, harmonic oscillators 
Week 9
11/10  Mid-term Exam (no class on 11/12) 
Week 10
11/17,11/19  Ideal polyatomic gas 
Week 11
11/24,11/26  Chemical equilibrium 
Week 12
12/01,12/03  Ising model 
Week 13
12/08,12/10  Phase transitions 
Week 14
12/15,12/17  Imperfect gas 
Week 15
12/22,12/24  Liquid theory 
Week 16
12/29,12/31  Electrolytes 
Week 17
1/05,1/07  Brownian motion 
Week 18
01/12  Final exam